Search results for "Liquid crystal shells"

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Dynamic tuning of the director field in liquid crystal shells using block copolymers

2020

When an orientationally ordered system, like a nematic liquid crystal (LC), is confined on a self-closing spherical shell, topological constraints arise with intriguing consequences that depend critically on how the LC is aligned in the shell. We demonstrate reversible dynamic tuning of the alignment, and thereby the topology, of nematic LC shells stabilized by the nonionic amphiphilic block copolymer Pluronic F127. Deep in the nematic phase, the director (the average molecule orientation) is tangential to the interface, but upon approaching the temperature TNI of the nematic– isotropic transition, the director realigns to normal. We link this to a delicate interplay between an interfacial …

medicine.medical_specialty: Physics [G04] [Physical chemical mathematical & earth Sciences]Shell (structure)Topological dynamics02 engineering and technology01 natural sciencessurfactantsSpherical shellTopological defectsTopological defectLiquid crystal shellsLiquid crystalPhase (matter)0103 physical sciencesmedicineQA010306 general physicsTopology (chemistry)Boundary conditionsIsotropy021001 nanoscience & nanotechnologyCondensed Matter::Soft Condensed Matter: Physique [G04] [Physique chimie mathématiques & sciences de la terre]Chemical physics0210 nano-technologyConfinementPhysical Review Research
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